[Platinum]

For people on a 64 bit machine:

START > RUN > "C:\Program Files (x86)\Skype\Phone\Skype.exe" /secondary

You know that by default it should create a shortcut to that location already?

Source:
""C:\Program Files (x86)\Skype\Phone\Skype.exe"

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I have to tell you that this isn't working for me. I have Windows 7 Ultimate 64 bit and when I click the shortcut again it simply opens the one that was already opened.